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Potassium Permanganate SDS MSDS Sheet, Suppliers and Manufacturers' Represantative

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Potassium Permanganate SDS Safety Data Sheet
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Product Name: Potassium Permanganate
Chemical Name:
Potassium Permanganate
CAS Number: 7722-64-7
Formula: KMnO4
Synonyms: Permanganic acid, potassium salt
Recommended usage: Industrial Manufacturing.

Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
US: 1-800-535-5053 
International: 352-323-3500


GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 2
Acute toxicity, oral Category 4
Acute toxicity, dermal Category 4
Serious eye damage/eye irritation Category 2B
Hazardous to the aquatic environment, acute hazard Category 1

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizing Solid
Oxidizing Solid
GHS Label Elements
GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

Signal Word: Warning

Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H320: Causes eye irritation.
H400: Very toxic to aquatic life.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P362: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use dry chemical, CO2 or appropriate foam for extinction.
P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
N Dangerous for the environment, R50/53
O Oxidizing, R 8
Xn Harmful, R22
C Corrosive R34


Ingredient: Potassium Permanganate
CAS No.: 7722-64-7
Percent: 90 - 100%


Emergency and First Aid Procedures:
Eyes - Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention at once.
Ingestion - If Potassium permanganate is swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Keep person warm and quiet, and get medical attention at once.


Extinguisher Media: Use dry chemical, CO2 or appropriate foam.
Auto ignition Temperature: N/A
Special Firefighting Procedures: Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: Potassium permanganate is strong oxidizer. Contact with combustible materials, flammable materials or powdered metals can cause fire or explosion.


Steps to be Taken in Case Material is Released or Spilled: Ventilate area of spill. Clean-up personnel should wear proper protective equipment. Avoid creating dust. Sweep or scoop up and containerize for disposal.


Precautions to be taken in Handling or Storing: Keep Potassium permanganate container tightly closed.
Other Precautions: Store separately and away from flammable and combustible materials.


Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation.
Respiratory Protection (Specify Type): None needed under normal conditions of use with adequate ventilation.
NIOSH approved equipment should be worn if PELs are exceeded.
Ventilation: Local Exhaust: Yes
Mechanical (General): Yes
Special: No
Protective Gloves: Rubber, neoprene, PVC, or equivalent.
Eye Protection: Splash proof chemical safety goggles should be worn at all times.
Other Protective Clothing or Equipment: Lab apron, eye wash, and safety shower.

Exposure Limits:
Chemical Name: Manganese and inorganic compounds, as Mn
ACGIH (TLV): TWA : 0.2 mg/m3(A4)
OSHA (PEL) : STEL: C 5 mg/m3
NIOSH (REL): TWA: 1 mg/m3 / STEL: 3 mg/m3


Molecular Weight: 158.04
Melting Point: Approximately 240C
Boiling Point: N/A
Vapor Pressure: N/A
Vapor Density (Air=1): 5.4
Specific Gravity(H2O=1): 2.7
Percent Volatile by Volume: 0 (21C)
Evaporation Rate(H2O=1): N/A
Solubility in Water: Moderate
Appearance and Odor: Potassium permanganate is dark purple to bronze crystals, odorless


Stability: Potassium permanganate is stable
Conditions to Avoid: Heat
Incompatibility (Materials to Avoid): Organic materials, combustible materials, strong reducing agents, strong acids, peroxides, alcohols, chemically active metals.
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur


Toxicity Data: Oral Rat LD50: 750 mg/kg
Carcinogenicity: This substance has no evidence of carcinogenic properties.


EPA Waste Numbers: D001

LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss), 96 h): 0.267 - 0.442 mg/l Mortality
LC 50 (Striped bass (Morone saxatilis), 96 h): 0.348 mg/l Mortality
LC 50 (Bluegill (Lepomis macrochirus), 96 h): 0.713 - 0.959 mg/l Mortality
Toxicity to fish, Gambusia affinis (fish, fresh water), LC100 = 18 mg/L/24 hours
Toxicity to daphnia and other aquatic invertebrates: Daphnia magna (Crustacea), EC0 = >0.63 mg/L
Toxicity to algae: Anabaena sp. (Algae), EC50 = <0.5 mg/L/18 days/growth rate
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Mobility in soil: No data available


Waste Disposal Methods: Dispose in accordance with all applicable regulations.


USA (Land, DOT) and Canada (TDG):
UN Number: UN 1490
Proper Shipping Name: Potassium permanganate
Hazard Class: Oxidizer
Packing Group: II
Division: 5.1
Product packaging containing more than 100 pounds
UN Number: UN 1490
Proper Shipping Name: Potassium permanganate, RQ
Hazard Class: Oxidizer
Packing Group: II
Division: 5.1
Additional Info.: If this product is spilled or leaked into the environment, the CERCLA (40 CFR 302.4) reportable quantity is 100 lbs, and requires National Response Center notification within United States of America.
UN number: UN 1490
Proper Shipping Name: Potassium permanganate
Transport hazard class(es): 5.1
Marine Pollutant: No
Packing group: II


HMIS (Perceived)
: Health Hazard: 2; Fire Hazard: 0; Reactivity: 0; Personal Protection: j
NFPA (Perceived): Health: 1; Flammability: 0; Reactivity: 0
Protective Equipment: Gloves, Synthetic apron, Vapor and dust respirator, Splash goggles.
TSCA: CAS# 7722-64-7 is listed on the TSCA inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: CAS# 7722-64-7: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances: None of the chemicals in this product have a TPQ.
SARA Codes CAS # 7722-64-7: acute, flammable.
Section 313: This material contains Permanganic permanganate (listed as Manganese), 100%, (CAS# 7722-64-7) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act: CAS# 7722-64-7 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Connecticut carcinogen reporting list.: Potassium permanganate
Illinois toxic substances disclosure to employee act: Potassium permanganate
Illinois chemical safety act: Potassium permanganate
New York release reporting list: Potassium permanganate
Rhode Island RTK hazardous substances: Potassium permanganate
Pennsylvania RTK: Potassium permanganate
Massachusetts RTK: Potassium permanganate, Massachusetts spill list: Potassium permanganate
New Jersey: Potassium permanganate, New Jersey spill list: Potassium permanganate Louisiana spill reporting: Potassium permanganate
California Director's list of Hazardous Substances: Potassium permanganate

WHMIS (Canada): CLASS C: Oxidizing material. CLASS E: Corrosive solid.


EINECS EC Number: 231-760-3
European Labeling in Accordance with EC Directives
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H320: Causes eye irritation.
H400: Very toxic to aquatic life.

C = Corrosive
N = Dangerous for the environment
O = Oxidizing
Xn = Harmful
R 8 = Contact with combustible material may cause fire.
R22 = Harmful if swallowed.
R34 = Causes burns.
R50/53=  Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases: S 60 This material and/or its container must be disposed of as hazardous waste.
S 61 Avoid release to the environment.

Prepared by AJK on 20 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Potassium Permanganate Manufacturers:

Finoric LLC
Beasley Houston Pleasanton Midland, Texas, USA.
Also Oklahoma, OK and Williston, ND USA

Tel: 1-855-346-6742 (1-855-FINORIC)

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31 May, 2021