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Phthalic Anhydride Manufacturers SDS MSDS Sheet

CAS No.: 85-44-9, EINECS EC number: 201-607-5, Molecular Weight: 148.13, Chemical Formula: C8H4O3

FInOrIC, etymologically derived from our business line of Fine Inorganic, Organic and Industrial Chemicals, is the internationally preferred source for Chemicals. With customers in 55 countries across 5 continents, we source and sell most chemicals. Backed by owned full fledged chemical manufacturing facilities in Midland & Houston Area Texas  with associated manufacturing sites in India, Dubai, China and USA we are a truly multi-national chemical manufacturer & distributor. Fracturing and Fracking Industry can rely on our 24x7 - 365days service including week-end deliveries.

Most of our or our partner facilities are either FDA-cGMP certified, ISO-9001:2008 certified, Halal and/or Kosher certified, REACH pre-registered ISO-22000:2005 HACCP.

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Specifications of Phthalic Anhydride Manufacturers

Phthalic Anhydride
Powder Granules Flakes Crystals
Phthalic Anhydride

Phthalic Anhydride SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: 1,3-Isobenzofurandione; 1, 2-benzenedicarboxylic acid anhydride; 1, 3-dioxophthalan.
CAS No.:
85-44-9
Einecs EC Number: 201-607-5
Molecular Formula: C8H4O3
Molecular Weight: 148.13
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4)
Skin irritation (Category 2)
Serious eye damage (Category 1)
Respiratory sensitization (Category 1),
Skin sensitization (Category 1),
Specific target organ toxicity - single exposure (Category 3), Respiratory system

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Health Hazard
Health Hazard
GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H302: Harmful if swallowed.
H315: Causes Skin Irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335: May cause respiratory irritation

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P285: In case of inadequate ventilation wear respiratory protection.
P314: Get medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332 + P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice / attention.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful, Xi Irritant.
R22 Harmful if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R41 Risk of serious damage to eyes
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Phthalic Anhydride (contains less than 0.05 percent maleic anhydride or maleic acid).
CAS No.: 85-44-9
Einecs EC Number: 201-607-5
Percent: 98-100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If Phthalic Anhydride is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Do not induce vomiting unless as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact:
Remove contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Notes to Physician: Treat symptomatically and supportively.

5. Fire Fighting Measures

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Auto-Ignition Temperature: 570°C (1058°F)
Flash Points: CLOSED CUP: 151.67°C (305°F). OPEN CUP: 165°C (329°F).
Flammable Limits: LOWER: 1.7% UPPER: 10.4%
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, fog or carbon dioxide.
Products of Combustion: These products are fumes and carbon oxides (CO, CO2).
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
NFPA: Health 3, Flammability 1,  Instability 0, Physical hazards N/A
Protective Equipment: Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.

7. Handling and Storage

Keep Phthalic Anhydride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of Phthalic Anhydride may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
OSHA (USA): 2 ppm TWA; 12 mg/m3 TWA
ACGIH: 1 ppm TWA
NIOSH: 1 ppm TWA; 6 mg/m3 TWA
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Phthalic Anhydride is white to off-white flakes, granules, crystals, powder.
Odor: Faint odor.
Solubility: Slightly soluble in water.
Density: 1.590 @ 20C/4C
pH: -.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 284-286C.
Melting Point: It is melting at 130-133C.
Vapor Density (Air=1): 5.7
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
Molecular Weight: 148.13
Molecular Formula: C8H4O3

10. Stability and Reactivity

Stability: Phthalic Anhydride is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Fumes with Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Heat, Strong oxidizers, sodium nitrate, sodium nitrite, nitric acid.
Conditions to Avoid: Heat, dusting and incompatibles.

11. Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Oral, rat: LD50 = 1530 mg/kg;
Inhalation, rat: LC50 = >210 mg/m3/1H;
Oral, mouse: LD50 = 1500 mg/kg;
Skin, rabbit: LD50 = >10 gm/kg;
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.

12. Ecological Information

Toxicity to fish: semi-static test LC50 - Danio rerio (zebra fish) - 560 mg/l - 7 d
Toxicity to daphnia and other aquatic invertebrates: Immobilization EC50 - Daphnia magna (Water flea) - > 640 mg/l - 48 h
Toxicity to algae: EC50 - Pseudokirchneriella subcapitata (green algae) - 60 - 350 mg/l - 96 h
Environmental Fate: Sufficient information is not available. When released into the soil, Phthalic Anhydride is expected to leach into groundwater. When released into the soil, this material is expected to biodegrade. When released into water, this material is expected to biodegrade. This material is not expected to significantly bio accumulate.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Phthalic Anhydride in accordance with legal requirements.

14. Transport Information

The product is no dangerous good in terms of the ADR/RID according to EU regulations or directives and the Austrian „Gefahrgutbeförderungsgesetz”. Contents of maleic anhydride or maleic acid below 0,05 % (w/w).
US DOT has Phthalic anhydride not classified as Class 8 Corrosive, if it contains not more than 0.05 percent maleic anhydride. Our product does not contain less than 0.05 percent maleic anhydride.

Land Transportation (ADR/RID) / Inland Waterway Transport (AND(R))
UN number: Not regulated as a hazardous material
Proper shipping name: PHTHALIC ANHYDRIDE
Marine Transport (IMDG)
UN number: Not regulated as a hazardous material
Proper shipping name: PHTHALIC ANHYDRIDE
Environmental Hazard: No
Air Transport (ICAO/IATA)
UN number: Not regulated as a hazardous material
Proper shipping name: PHTHALIC ANHYDRIDE

15. Regulatory Information

USA:
TSCA 8(b) inventory
: Phthalic Anhydride
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Health & Safety Reporting List:
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules:
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b:
CAS# 85-44-9: 4/12b/4a
TSCA Significant New Use Rule:
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
CAS# 85-44-9: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 85-44-9: acute, chronic, reactive.
Section 313
This material contains Phthalic Anhydride (CAS# 85-44-9, 99%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 85-44-9 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 85-44-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed.

WGK (Water Danger/Protection): CAS# 85-44-9: 0

HMIS (Perceived): Health Hazard: 3, Fire Hazard: 1, Reactivity: 0, Personal Protection: j
NFPA (Perceived): Health: 3, Flammability: 1, Reactivity: 0
Protective Equipment: Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.

Canada WHMIS: CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid.
CAS# 85-44-9 is listed on Canada's DSL List. CAS# 85-44-9 is listed on Canada's DSL List.
CAS# 85-44-9 is listed on Canada's Ingredient Disclosure List.

Australian Hazchem Code: No information found.
Poison Schedule: No information found.

16. Other Information

EINECS EC Number: 201-607-5
European Labeling in Accordance with EC Directives
H302 = Harmful if swallowed.
H315 = Causes Skin Irritation.
H317 = May cause an allergic skin reaction.
H318 = Causes serious eye damage
H334 = May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 = May cause respiratory irritation
Xn Harmful
Xi Irritant
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R41 Risk of serious damage to eyes
Prepared by AJK on 15 August 2016 - Printed on: 24 August 2016
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

EINECS EC Number: 201-607-5
European Labeling in Accordance with EC Directives
H302 = Harmful if swallowed.
H315 = Causes Skin Irritation.
H317 = May cause an allergic skin reaction.
H318 = Causes serious eye damage
H334 = May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 = May cause respiratory irritation

Xn Harmful
Xi Irritant
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R41 Risk of serious damage to eyes

Prepared by AJK on 15 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

We offer all grade, including powder, granules and flakes. We also offer Phthalic Acid.

Phthalic Anhydride Manufacturers:

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

Most products offered from our Midland & Houston, TX area warehouse

We solicit inquiries for processing (blending, making solutions, sieving) & re-bagging needs at our Houston & Midland facility on toll manufacturing basis.
We are looking for Technical Sales Representatives or Business Associates in New York, Chicago, Williston North Dakota, Mansfield Pennsylvania, Zanesville, Ohio and Los Angeles Area, USA.

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Palletized and Shrink Wrapped 25kg 50kg 55 lbs Export Import Palletized and Shrink Wrapped Drum Packing Phthalic Anhydride Manufacturers

Phthalic Anhydride Suppliers, Manufacturers, Exporters, Importers

12 April, 2017