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Phthalic Acid SDS MSDS Sheet

CAS No.: 88-99-3, EINECS EC number: 201-873-2; Molecular Weight: 166.14, Chemical Formula: C8H6O4

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Phthalic Acid Specifications

Phthalic Acid
Pure Crystals
Phthalic Acid

Phthalic Acid SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: 1,2-Benzenedicarboxylic acid; o-dicarboxybenzene; o-Benzenedicarboxylic acid;
CAS No.: 88-99-3
EINECS EC Number: 201-873-2
Molecular Formula: C6H4(CO2H)2
Molecular Weight: 166.13
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin irritation (Category 2)
Serious eye damage/eye irritation (Category 2A)
Specific target organ toxicity - single exposure, Target Organs - Respiratory system. (Category 3)

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xi Irritant R36/37/38
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

Carcinogenic Effects: Not available.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

3. Composition/Information on Ingredients

Ingredient: Phthalic Acid
CAS No.: 88-99-3
Percent: 90-100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If Phthalic Acid is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Flash Point: CLOSED CUP: 168C (334.4F).

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.

7. Handling and Storage

Keep Phthalic Acid in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of Phthalic Acid may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Phthalic Acid is white crystals.
Odor: Faint odor.
Solubility: Soluble in water.
Density: 1.590 @ 20C/4C
pH: < 7 Acidic.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 135C (275F) Decomposes.
Melting Point: It is melting at 190 C in a sealed tube (that prevents loss of water). In the open, the acid appears to melt at 210 C.
Vapor Density (Air=1): 5.7
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
Molecular Formula: C6H4(CO2H)2
Molecular Weight: 166.13

10. Stability and Reactivity

Stability: Phthalic Acid is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers, sodium nitrate, sodium nitrite, nitric acid.
Conditions to Avoid: Heat, dusting and incompatibles.

11. Toxicological Information

Oral rat LD50: 7900 mg/Kg
Oral mouse LD50: 2530 mg/Kg
--------\Cancer Lists\---------------- --------------
---------------- NTP Carcinogen---
Ingredient ----- Known -- Anticipated -- IARC Category
---------------- -------- ----------- -- -------------
Phthalic Acid -- No ----- No -------- -- None
(88-99-3)

12. Ecological Information

Environmental Fate: Sufficient information is not available. When released into the soil, Phthalic Acid is expected to leach into groundwater. When released into the soil, this material is expected to biodegrade. When released into water, this material is expected to biodegrade. This material is not expected to significantly bio accumulate.
Environmental Toxicity:
No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Phthalic Acid in accordance with legal requirements.

14. Transport Information

DOT: Not regulated as dangerous goods.
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

15. Regulatory Information

USA:
TSCA 8(b) inventory
: Phthalic acid
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
HMIS (Perceived):
Health Hazard: 3
Fire Hazard: 1
Reactivity: 0
Personal Protection: j

WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC)

Australian Hazchem Code: No information found.
Poison Schedule: No information found.

16. Other Information

EINECS EC Number: 201-873-2
European Labeling in Accordance with EC Directives
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.

Xi = Irritant
R36/37/38 = Irritating to eyes, respiratory system and skin.

Prepared by AJK on 15 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Phthalic Acid Manufacturers:

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

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