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Glutaraldehyde Solution SDS MSDS Sheet

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Glutaraldehyde has been listed as a component of hydraulic fracturing "fracking" fluid. It is a biocide. Bacterial growth can impair the production of oil and gas wells, and can be introduced into the formation from various sources including the source water, proppant, and polymer used in the hydraulic fracturing process. Glutaraldehyde is pumped as a liquid additive with the fracturing fluid to reduce or eliminate this source of formation and fracture conductivity damage.

Glutaraldehyde Manufacturers Specifications

Glutaraldehyde MSDS Sheet

Glutaraldehyde
Biogaurd, Biocide
Glutaraldehyde

Glutaraldehyde Solution SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Pentanedial, Glutardialdehyde, Glutaric acid dialdehyde, Glutaric aldehyde, Glutaric dialdehyde, 1,5-Pentanedial (for un-diluted material)
CAS No.: 111-30-8
EINECS EC Code: 203-856-5
Molecular Weight: 100.12 for un-diluted material.
Chemical Formula: CH2(CH2CHO)2 for un-diluted material.
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3)
Acute toxicity, Inhalation (Category 3)
Acute toxicity, Dermal (Category 4)
Skin corrosion (Category 1B)
Serious eye damage (Category 1)
Respiratory sensitisation (Category 1)
Skin sensitisation (Category 1)
Hazardous to the aquatic environment, acute hazard (Category 1)

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic
GHS Label Elements
Corrosive
Corrosive
GHS Label Elements
Health Hazard
Health Hazard
GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

Signal Word: Warning

Hazard Statements:
H290: May be corrosive to metals
H301: Toxic if swallowed
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction
H318: Causes serious eye damage.
H331: Toxic if inhaled
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
H400: Very toxic to aquatic life

Precautionary Statements
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P234 Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do no eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341 + P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P310 Immediately call a POISON CENTER or doctor/physician.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P363: Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T Toxic, Xi Irritant, C Corrosive, N Dangerous for the environment
R23/25 Toxic by inhalation and if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

3. Composition/Information on Ingredients

Ingredient: Glutaraldehyde 13-17% in water.
CAS No.: 111-30-8
EINECS EC Code: 203-856-5

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If Glutaraldehyde is inhaled, it will cause irritation and damage to nose and throat. It can cause headache, bleeding from nose coughing and chest discomfort. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: It will cause irritation and burns to mouth, digestive tract and stomach. It may lead to pain, nausea, vomitting, and even collapse. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe damage to eyes. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Fire: Flash point: NA.
Auto ignition temperature: NA
Toxic fumes, carbon dioxide and carbon monoxide may be formed in fire.
Explosion: Not known.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Small Spill: Mop and pick up the material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid mist formation. Keep away from heat. Keep away from sources of ignition. The concentration of Glutaraldehyde can be brought down by neutralizing with 1.25 moles of Diammonium Phosphate. Provide ventilation. Contact Environment Agency.
Wear full protective equipment and ensure proper ventilation.

7. Handling and Storage

Keep away from heat and source of fire preferably in a ventilated area. Keep in tightly closed container. Do not breathe mist or dust. Containers of Glutaraldehyde may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. Do not allow to freeze. Avoid contact. Do not store near food items or near Diammonium Phosphate.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: TWA: Long term (8 hours) & Short term(15 minutes) WEL is 0.05 ppm.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Colorless liquid.
Odor: typical aldehyde smell.
Solubility: miscible with water
Specific Gravity: 1.025 approximate
pH: NA.
% Volatiles by volume @ 21C (70F): NA
Boiling Point: >100C
Melting Point: - NA.
 

Molecular Weight: 100.12 for un-diluted material.
Molecular Formula: CH2(CH2CHO)2 for un-diluted material.
Vapor Pressure (mm Hg): NA
Evaporation Rate (BuAc=1): -

10. Stability and Reactivity

Stability: Glutaraldehyde is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide and toxic fumes may form when heated to decomposition.
Hazardous Polymerization: Not reported.
Incompatibilities: Metals, strong acids & alkalies, oxidizing & reducing agents, heat and sparks.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

Oral rat LD50: 134 mg/kg
The product is not listed as carcinogen.

12. Ecological Information

Environmental Toxicity: Toxic to fish and aquatic life.
Biodegradability: The product is easily biodegradable.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

DOT (US)
UN Number: 3265
Proper shipping name: Corrosive liquid, acidic, organic. NOS (contains glutaraldehyde)
Class: 8
Packing group: II

IMDG
UN Number: 3265
Proper shipping name: Corrosive liquid, acidic, organic. NOS (contains glutaraldehyde)
Class: 8
Packing group: II

IATA
--

15. Regulatory Information

USA:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
TSCA: CAS# 111-30-8 is listed on the TSCA Inventory.
TSCA Significant New Use Rule: None of the chemicals in this product have SNUR under TSCA.
CERLA Hazardous Substances and Corresponding RQs: None of the chemicals in this product have an RQ.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals are under a Chemical Test Rule.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312: Acute & Chronic.
California Prop 65: No Significant Risk Level: None of the chemicals in this product are listed.
Clean Air Act: This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act.
Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances, Priority Pollutants, or Toxic Pollutants under the CWA.

Canada WHMIS: CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC). CLASS E: Corrosive liquid.
Canada - DSL/NDSL: Cas# 111-30-8 is listed on Canada's DSL List.

HMIS (Perceived): Health Hazard: 2, Fire Hazard: 0, Reactivity: 0
NFPA (Perceived): Health: 2, Flammability: 0, Reactivity: 0

16. Other Information

EINECS EC Code: 203-856-5
European Labeling in Accordance with EC Directives
H290 = May be corrosive to metals.
H301 = Toxic if swallowed.
H312 = Harmful in contact with skin.
H315 = Causes skin irritation.
H317 = May cause an allergic skin reaction
H318 = Causes serious eye damage.
H331 = Toxic if inhaled.
H334 = May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H400 = Very toxic to aquatic life.

T = Toxic
Xi = Irritant
C = Corrosive
N = Dangerous for the environment
R23/25            = Toxic by inhalation and if swallowed.
R36/37/38 = Irritating to eyes, respiratory system and skin.
R51/53            = Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S22- Do not breathe dust.
S24- Avoid contact with skin.
S26- In case of contact with eyes, rinse immediately with plenty of water & seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection

Prepared by AJK on 15 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Glutaraldehyde Manufacturers

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

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