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Ammonium Bifluoride SDS MSDS Sheet of Supplier Manufacturers

CAS number1341-49-7, EINECS EC code number215-676-4, Molecular Weight57.04, Chemical Formula NH4HF2

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Specifications of Ammonium Bifluoride

Ammonium Bifluoride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Ammonium hydrogen difluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4
Molecular Weight: 57.04
Chemical Formula: NH4HF2
Relevant Uses: Fracturing and Industrial use only.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral: Category 3
Skin corrosion/irritation Category 1A, B, C
Serious eye damage/eye irritation Category 1
Specific target organ toxicity, repeated exposure Category 2

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

GHS Label Elements
Health Hazzard
Health Hazard

GHS Label Elements
corrosive.png
Corrosive

Signal Words: Danger

Hazard Statements:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements:
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P273: Avoid release to the environment.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well-ventilated area.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P:273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. P337+P313: If eye irritation persists get medical advice/attention.
Remove contact lenses if present and easy to do – continue rinsing.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403+P404: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T Toxic, Xn Harmful
R20,  R25, R41, R48
For the full text of the S-statement & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Ammonium Bifluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4
Percent: 95 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Ammonia, Nitrogen oxides, Hydrofluoric acid and fumes.
Fire: Ammonium Bifluoride is not considered to be a fire hazard.
Explosion: Ammonium Bifluoride is not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Ammonium Bifluoride is a poisonous solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Toxic! Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ammonium Bifluoride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Moist Ammonium Bifluoride and concentrated solutions can corrode steel.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
2.5 mg/m3 USA (OSHA) - Table Z-1 Limits for Air Contaminants
(Vacated) TWA: 2.5 mg/m3 OSHA PEL
TWA 2.5 mg/m3 ACGIH TLV
TWA: 2.5 mg/m3 NIOSH IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Ammonium Bifluoride is white crystals, powder or granules.
Odor: Pungent.
Solubility: It is freely soluble in water.
pH: 3.5.
Density: 1.5 g/mL
Molecular Weight
: 57.04
Chemical Formula: NH4HF2
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 240C
Melting Point: 125C
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Ammonium Bifluoride  is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic hydrogen fluoride fumes when heated to decomposition. It may form Ammonia, Nitrogen oxides and Hydrogen fluoride and Fluorine.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, strong acids and bases.
Conditions to Avoid
: Incompatibles and direct sunlight and moisture..

11. Toxicological Information

Acute toxicity
Toxic, and may be fatal, if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Cough, Shortness of breath, Headache, Nausea
Toxicity data
ORL-RAT LD50 130 mg kg-1
LD50 Intraperitoneal – rat – 31 mg/kg
LC50 – mouse – 342 mg/kg – 1 hour
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Toxicity to fish: Not available.
Toxicity to daphnia and other aquatic invertebrates: Not available.
Environmental Toxicity: Not available.
Toxicity of the Products of Biodegradation: Not available..

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

USA DOT, IMDG & Canada TDG Classification:
UN-Number: 1727 CLASS 8: Packing group: II
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID
IATA/ICAO
UN-Number: 1727 CLASS 8: Packing group: II
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID

15. Regulatory Information

USA:
TSCA 12(b): Not applicable
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazardous Categorization: Acute Health Hazard
Clean Water Act: Listed. Reportable Quantity 100 pounds.
Clean Air Act: Not applicable
CERCLA: Reportable Quantity 100 pounds.
California Proposition 65: This product does not contain any Proposition 65 chemicals
Listed by State Right to Know: Massachusetts, Pennsylvania, New Jersey Right

Canada WHMIS Hazard Class: D1B Toxic materials, E Corrosive material
Canadian Ingredient Disclosure List: listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

EINECS: EC Number: 215-676-4
European Labeling in Accordance with EC Directives:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.
Hazard Symbols: T = Toxic; Xn = Harmful
Risk Phrases: R 25 = Toxic if swallowed. R 20 Harmful by inhalation. R41 Risk of serious damage to eyes. R48 Danger of serious damage to health by prolonged exposure.
Safety Phrases: S 45 In case of accident or if you feel unwell, seek medical advice immediately. S28- After contact with skin, wash immediately with plenty of water. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S46- If swallowed, seek medical advice immediately.

Prepared by AJK on 15 September 2016 - Printed on: 13 September 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Manufacturers:

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

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12 April, 2017