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Acetic Acid Solution SDS, MSDS Sheet

CAS number 64-19-7, EINECS EC code number 200-580-7, Molecular Weight 60.05, Chemical Formula CH3COOH

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MSDS of Acetic Acid Solution
MSDS of Glacial Acetic Acid Manufacturers
Specifications of Acetic Acid Manufacturers

Acetic Acid Solution
Fracking or Fracturing Acid
Acetic Acid Solution

Acetic Acid Solution SDS, MSDS Sheet, Material Safety Data Sheet

Section 1 - Chemical Product and Company Identification

MSDS Name: Acetic Acid Solution
Synonyms: Ethanoic acid, Ethylic acid, Methanecarboxylic acid, Vinegar.
Recommended usage: Industrial Manufacturing.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

Section 2 - Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation (Category 1A, B, C) H314
Acute aquatic toxicity (Category 3) H402

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.

Precautionary statements:
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting equipment.
P242 - Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe mist, vapours, spray.
P264: Wash exposed skin thoroughly after handling.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P314: Get Medical advice/attention if you feel unwell.
P337+ P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction.
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to comply with local, state and federal regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
C Corrosive
R35 Causes severe burns.
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

Section 3 - Composition/Information on Ingredients

Chemical Name: Acetic Acid Solution
CAS#: 64-19-7
Percent: 99-100% on dry basis. Dilution is always with water.

Section 4 - First Aid Measures

Always consult a physician after the first aid is given.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flash Point: 40C 104F for glacial material.
Auto Ignition Temperature: 463C 865F for glacial material.
Extinguishing Media: Use DRY chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
NFPA CODE: H-3, F-2, R-0

Section 6 - Accidental Release Measures

Spills/Leaks: Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Contain the spill with sand or other inert absorbent material, neutralize with sodium bicarbonate or calcium hydroxide, and deposit in a sealed bag or container. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Cover with material such as dry soda ash or calcium carbonate and place into a closed container for disposal.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container of tightly closed. Avoid ingestion and inhalation. Do not allow contact with heat. Do not breathe vapors or spray mist.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from heat and flames.

Section 8 - Exposure Controls, Personal Protection

Airborne Exposure Limits: Airborne Exposure Limits:
OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA) for glacial material.
ACGIH Threshold Limit Value (TLV): 10 ppm (TWA); 15 ppm (STEL)for glacial material.
NIOSH 10ppm TWA; 25 mg/m3 TWA 50ppm IDLH for glacial material.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

Section 9 - Physical and Chemical Properties

Appearance: Clear Liquid
Odor: Vinegar odor
Solubility: Soluble in water
Specific Gravity: 1.049 for glacial material.
pH: 2 for 1% solution, 2.4 (1.0M solution)
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 118.C (244.5F) for glacial material.
Melting Point:
16.6C (61.9F) for glacial material.
Molecular Formula:C2H4O2 for glacial material.
Molecular Weight:60.05 for glacial material.

Section 10 - Stability and Reactivity

Chemical Stability: Acetic acid solution is stable under normal temperatures and pressures. It is hygroscopic.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to heat, spark, moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

Acute oral toxicity (LD50): 16550 mg/kg (Rat) (Calculated value for the mixture).
Acute oral toxicity (LD50): 3310 mg/kg [Rat] for Glacial Material.
Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit] for Glacial Material.
Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse] for Glacial Material.
LC50 Inhalation - rat - 4 h - 11.4 mg/l 4 hours

The material is not reported as a carcinogen.

Section 12 - Ecological Information

Environmental Fate: The material will readily biodegrade.
Environmental Toxicity: (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm - 96 hours [Daphnia] for glacial material.

Section 13 - Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of and unused contents in accordance with local requirements.

Section 14 - Transport Information

DOT (USA) & ADR/RID
UN number: 2790
Class: 8
Packing group: II
Proper shipping name: Acetic acid, solution
Reportable Quantity (RQ): 6250 lbs
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2790
Class: 8
Packing group: II
Proper shipping name: Acetic acid, solution
Reportable Quantity (RQ): 6250 lbs
Marine pollutant: No
IATA
UN number: 2790
Class: 8
Packing group: II
Proper shipping name: Acetic acid, solution
Reportable Quantity (RQ): 6250 lbs

Section 15 - Regulatory Information

USA FEDERAL
TSCA
: CAS# 64-19-7 is listed on the TSCA inventory.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
SARA Section 302 (RQ): CAS# 64-19-7: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ): None of the chemicals in this product have a TPQ.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard
Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act: CAS# 64-19-7 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

USA STATE
CAS# 64-19-7 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Canada
CAS# 64-19-7 is listed on Canada's DSL List.
This product has a WHMIS classification of B3, E.
CAS# 64-19-7 is listed on Canada's Ingredient Disclosure List.
WHMIS (Canada): CLASS B-3: Combustible liquid with a flash point between 37.8C (100F) and 93.3C (200F). CLASS E: Corrosive liquid.

HMIS (Perceived): Health Hazard: 3; Fire Hazard: 2; Reactivity: 0; Personal Protection: E
NFPA (Perceived): Health: 3; Flammability: 2; Reactivity: 0
Protective Equipment:
Gloves (impervious). Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate
respirator when ventilation is inadequate. Safety glasses.

Section 16 - Additional Information

EINECS: 200-580-7.
European Labeling in Accordance with EC Directives
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.

Hazard Symbols: C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases: S 23 Do not inhale gas/fumes/vapor/spray. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Prepared by AJK on 15 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Acetic Acid Solution Manufacturers:

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

Most products offered from our Houston & Midland Texas area warehouse

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12 April, 2017