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Vanadium Chloride (IV) Vanadium Tetrachloride SDS MSDS Sheet

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Specifications of VCl2, VCl3, VCL4 Vanadium Dichloride Vanadium Chloride Trichloride & Vanadium Tetrachloride Manufacturers

Vanadium Chloride (IV)
Technical & Pure Vanadium Tetrachloride VCl4 ACS AR Crystals
Vanadium Chloride IV VCl4

Vanadium Chloride (IV) SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Vanadium tetrachloride
CAS No.: 7632-51-1
EINECS EC Number: 231-561-1
Molecular Weight: 192.75
Chemical Formula: VCl4
Intended Use: Industrial Manufacturing.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable solids Category 1
Substances & Mixtures which in contact with water, emit flammable gases Category 2
Acute oral toxicity Category 3
Acute toxicity, dermal Category 3
Skin corrosion/irritation Category 1A, B, C
Serious eye damage/eye irritation Category 2A
Acute toxicity, inhalation Category 3

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic
GHS Label Elements
Emits Flamable Gases with Water
Emits Flammable
Gases with Water
GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H228: Flammable solid.
H261: In contact with water releases flammable gas.
H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces No smoking.
P223: Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231: Handle under inert gas.
P232: Protect from moisture.
P233: Keep container tightly closed.
P234: Keep only in original container.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use dry chemical, alcohol foam, or carbon dioxide for extinction. Avoid water.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well ventilated place.
P404: Store in a closed container.
P405: Store locked up.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Flammable
T Toxic
C Corrosive
Risk Phrases: R-11 Highly flammable.
R-15 Contact with water liberates extremely flammable gases.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed

OSHA Hazards: Toxic if ingested or inhaled. Corrosive.

HMIS (Perceived)
Health hazard: 3
Flammability: 0
Physical hazards: 0
NFPA (Perceived)
Health hazard: 3
Fire: 0
Reactivity Hazard: 2

3. Composition/Information on Ingredients

Ingredient: Vanadium Chloride (IV)
CAS No.: 7632-51-1
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.

5. Fire Fighting Measures

Flammability of the Product: The product is not ordinarily flammable, if stored tight. If exposed it can releases flammable gas.
Auto-Ignition Temperature: NA.
Flash Points: NA.
Flammable Limits: NA.
Products of Combustion: It may emit hydrogen chloride fumes and vanadium oxide when heated to decomposition.
Explosion: Not likely. Contact with acids may emit flammable hydrogen gas.
Fire Extinguishing Media: Avoid Water. Use means suitable for extinguishing surrounding fire. Dry chemical, alcohol foam, or carbon dioxide.
Special Information
 In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by swabbing and then spreading water on the contaminated surface and allow evacuating through the sanitary system.

Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately. Provide ventilation. Do not expose spill to water.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Vanadium Chloride (IV) in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage or contact with moisture, oxidizing material.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established. Leave the contaminated area in 15 minutes.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Vanadium Chloride (IV) is red to brown liquid.
Odor: Acrid; Typical.
Solubility: Reacts with water.
pH: -- at 1% solution at 25 C (77F)
Density: 1.8 gm/cc. It varies.
Molecular Weight: 192.75
Molecular Formula: VCl4
% Volatiles by volume @ 21C (70F): -
Boiling Point: 154C
Melting Point: -28C minus.
Vapor Density (Air=1)
: No information found
Vapor Pressure (mm Hg): 6mm Hg at 20C
Evaporation Rate (BuAc=1): No information found

10. Stability and Reactivity

Stability: Vanadium Chloride (IV) is unstable. Combines vigorously or explosively with water.
Hazardous Decomposition Products: It emits toxic hydrogen chloride fumes vanadium oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Moisture & water, Polar solvents, Plastics, Oxidizing agents, Strong acids, Strong reducing agents, Metals.
Conditions to Avoid
: Moisture, Heat, Incompatibles.

11. Toxicological Information

Toxicity to Animals:
Oral, rat: LD50 160 mg/kg
Oral, rabbit: LD50 = - mg/kg
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Environmental Toxicity: Not available.
Biodegradability
: -
BOD5 and COD: Not available.
Environmental Fate: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

14. Transport Information

DOT (USA)
UN number: 2444; Class: 8; Packing group: I
Proper shipping name: Vanadium tetrachloride
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2444; Class: 8; Packing group: I; EMS-No: F-A, S-B
Proper shipping name: Vanadium tetrachloride
Marine pollutant: No
Poison Inhalation Hazard: No
IATA
UN number: 2444; Class: 8; Packing group: I; EMS-No: F-A, S-B
Proper shipping name: Vanadium tetrachloride
Not permitted by passenger transport.

15. Regulatory Information

USA:
OSHA Hazards
: Toxic if ingested or inhaled. Corrosive.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: Listed.
SARA 311/312 Hazards: Acute Health Hazards.
TSCA: - is on the TSCA Inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Massachusetts Right To Know Components: Vanadium (IV) chloride, CAS-No.: 7632-51-1
Pennsylvania Right To Know Components: Vanadium (IV) chloride, CAS-No.: 7632-51-1
New Jersey Right to Know Components: Vanadium (IV) chloride, CAS-No.: 7632-51-1

Canada - DSL/NDSL: CAS# - is listed on Canada's DSL List.
Canadian WHMIS Classifications: D1A Very toxic materials; E Corrosive material; F Dangerously reactive material

Australian Hazchem Code: -
Poison Schedule: -

16. Other Information

EINECS EC Number: 231-561-1
European Labeling in Accordance with EC Directives
H228: Flammable solid.
H261: In contact with water releases flammable gas.
H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.

F Flammable
T Toxic
C Corrosive
Risk Phrases:
R-11 Highly flammable.
R-15 Contact with water liberates extremely flammable gases.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
Safety Phrases: S 25 Avoid contact with eyes. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 28A After contact with skin, wash immediately with plenty of water.

Prepared by AJK on 20 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Vanadium Chloride Manufacturers:

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

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