30 March, 2018
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Glycerol, glycerine or glycerin SDS MSDS Sheet, Suppliers and Manufacturers' Represantative
CAS number 56-81-5, EINECS EC code number 200-289-5, Molecular Weight 92.1, Chemical Formula C3H8O3
FInOrIC, etymologically derived from our business line of Fine Inorganic, Organic and Industrial Chemicals, is the internationally preferred source for Chemicals. With customers in 55 countries across 5 continents, we source and sell most chemicals. Backed by owned full fledged chemical manufacturing facilities in Midland & Houston Area Texas with associated manufacturing sites in India, Dubai, China and USA we are a truly multi-national chemical manufacturer & distributor. Fracturing and Fracking Industry can rely on our 24x7 - 365days service including week-end deliveries.
Most of our or our partner facilities are either FDA-cGMP certified, ISO-9001:2008 certified, Halal and/or Kosher certified, REACH pre-registered ISO-22000:2005 HACCP.
Specifications of Glycerin Manufacturers
Glycerin SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
Section 1 - Chemical Product and Company Identification
MSDS Name: Glycerin
Synonyms: 1,2,3-Propanetriol; Glycerol, Glycerine, Glyceritol, Glycic Alcohol.
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA
In case of emergency contact:
Section 2 - Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: None
Hazards not otherwise classified (HNOC):
May cause mild skin irritation.
May cause mild eye irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
Health Hazard: 1
Fire Hazard: 1
Section 3 - Composition, Information on Ingredients
Chemical Name: Glycerin and Glycerol.
EINECS EC code number: 200-289-5
Percent: 95-100% (Dilution is always with water.
Section 4 - First Aid Measures
Always consult a physician after the first aid is given.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Flammable. Explosive in presence of oxidizing materials.
Flash Point: CLOSED CUP: 160°C (320°F).
Auto Ignition Temperature: 370°C (698°F)
Extinguishing Media: Use Water, dry chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
NFPA CODE: health: 1; flammability: 1; instability: 0.
Glycerin is incompatible with strong oxidizers.
Section 6 - Accidental Release MeasuresSpills/Leaks: Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Contain the spill with sand or other inert absorbent material, neutralize with sodium bicarbonate or calcium hydroxide, and deposit in a sealed bag or container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container of Glycerin tightly closed. Avoid ingestion and inhalation. Do not allow contact with heat. Do not breathe vapors or spray mist.
Storage: Store Glycerin in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store Glycerin protected from heat and incompatible materials.
Section 8 - Exposure Controls, Personal Protection
Airborne Exposure Limits:
ACGIH TLV is 10mg/m3.
OSHA PEL is 10 mg/m3 total, 5 mg/m3 respirable.
NIOSH Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Glycerin.
Section 9 - Physical and Chemical Properties
Appearance: Clear Liquid
Odor: Faint odor
Solubility: Miscible in water
Specific Gravity: 1.26g/cm3 @ 20C
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 290 deg C ( 554F)
Melting Point: 17.8C
Molecular Formula: C3H8O3
Molecular Weight: 92.1
Section 10 - Stability and Reactivity
Chemical Stability: Glycerin is stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, exposure to heat, spark.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
Acute oral toxicity (LD50): 4090 mg/kg [Mouse] 4 hours.
Acute oral toxicity (LD50): 12600 mg/kg [Rat] 4 hours.
Acute dermal toxicity (LD50): 21900 mg/kg [Rat] 4 hours.
Acute dermal toxicity (LD50): 10000 mg/kg [Rabbit] 4 hours.
Acute toxicity of the mist (LC50): >570 mg/m3 1 hours [Rat].
The material is not reported as a carcinogen.
Section 12 - Ecological Information
Environmental Fate: The material will readily biodegrade.
Environmental Toxicity: LC50 (24 hour(s), Goldfish) 5000 mg/l; LC50 (96 Hr.) rainbow trout = 50-67 mg/L; EC50 (24 hour(s), Daphnia magna 500mg/L
Section 13 - Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Glycerin and unused contents in accordance with local requirements.
Section 14 - Transport Information
DOT (USA) & ADR/RID
Section 15 - Regulatory Information
CAS# 56-81-5 is listed on the TSCA inventory.
Not Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this material have an RQ.
No chemicals are reportable under Section 313.
SARA 311/312 Hazards
Acute Health Hazard Immediate
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 56-81-5 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
CAS# 56-81-5 Glycerine can be found on the following state right to know lists:Pennsylvania, Minnesota, Massachusetts.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
CAS# 56-81-5 is listed on Canada's DSL List.
This product does not WHMIS classification.
CAS# 56-81-5 is not listed on Canada's Ingredient Disclosure List.
WHMIS (Canada): CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.
European/International Regulations European Labeling in Accordance with EC Directives
EINECS: 200-289-5. This product is on the European Inventory of Existing Commercial Chemical Substances.
Section 16 - Additional Information
Prepared by AJK on 15 August 2016
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Glycerol, glycerine or glycerin Manufacturers:
Houston, Midland & Pleasanton, Texas, USA.
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