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DETA, DTPMP Phosphonate, diethylenetriamine penta methylene phosphonic acid SDS - MSDS Sheet

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DETA diethylenetriamine penta(methylene phosphonic acid)
DTPMP Phosphonate, Fracking or Fracturing Acid
DTTMP DETA Phosphonate Scale Inhibitor

 

DETA Phosphonate or DTPMP Phosphonate or diethylenetriamine penta(methylene phosphonic acid) SDS Safety Data Sheet
MSDS Material Safety Data Sheet

1. Product & Company Identification

Synonyms: DETA Phosphonate, diethylenetriamine penta(methylene phosphonic acid)
CAS No.: 15827-60-8
Molecular Weight: 573.20
Chemical Formula: C9H28N3O15P5
Relevant Uses: Scale Inhibitor

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA
Tel: 1-855-346-6742

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500
Contract #: 104662

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Corrosive To Metals, Category 1
Skin corrosion/irritation Category 1A, B, C
Serious eye damage/eye irritation Category 1
Hazardous to the aquatic environment, long-term hazard Category 4

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Word: Warning

Hazard Statements:
H290 - May be corrosive to metals.
H314 - Causes severe skin burns and eye damage.
H318 - Causes serious eye damage.
H413 - May cause long lasting harmful effects to aquatic life.

Precautionary Statements
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash hands thoroughly after handling.
P264: Wash thoroughly after handling.
P273: Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P310: Immediately call a POISON CENTER or doctor/physician
P390: Absorb spillage to prevent material damage.
P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor.
P405: Store locked up.
P406: Store in corrosive resistant/ container with a resistant inner liner.
P405 - Store locked up.
P501: Dispose of contents/container  in accordance with all federal, state and local regulations

OSHA Status: This material is classified as hazardous under OSHA regulations
Target Organs: None Known
Carcinogenic Effects: Not available.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
C Corrosive, Xi Irritant R41, R37/38
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Diethylenetriaminepenta (methylenephosphonic acid)
CAS No.: 15827-60-8
Percent: 45-55%
Ingredient: Hydrochloric acid  (Hydrogen chloride)
CAS No.: 7647-01-0
Percent: 5-15%

4. FIRST AID MEASURES

Always seek medical attention after first aid measures are provided.

After inhalation: Move victim to fresh air. In case of respiratory difficulties seek medical attention.
In case of skin contact: After contact with skin, wash immediately with plenty of water. Change contaminated clothing. In case of skin reactions, consult a physician.
After eye contact:       Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Remove contact lenses. Subsequently seek the immediate attention of an ophthalmologist.
After swallowing: Rinse mouth and drink large quantities of water. Consult physician.

5. FIRE FIGHTING MEASURES

Fire and explosion hazard: Slight fire hazard. Dust/air mixtures may ignite or explode.
Extinguishing media: Regular dry chemical, carbon dioxide, water, and regular foam.
Fire fighting: Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Use extinguishing agents appropriate for surrounding fire. Do not get water directly on material.
Large fires: Flood with fine water spray. Reduce vapors with water spray. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Occupational spills: Do not touch spilled material. Stop leak if possible without personal risk.
Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal.
Small dry spills: Move containers away from spill to a safe area.
Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry.

7. HANDLING AND STORAGE

Handling:  Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of material from eyes, skin and clothing. Emptied containers retain vapor and product residue. Observe all recommended safety precautions until container is cleaned, reconditioned or destroyed. The reuse of this material's container for non industrial purposes is prohibited and any reuse must be in consideration of the data provided in this material safety data sheet.
Storage: Store in cool, dry, well ventilated area. Product is stable under normal conditions of handling and storage. Emptied containers retain vapor and product residue. Observe all recommended safety precautions until container is cleaned, reconditioned, or destroyed. The reuse of this material’s container for non-industrial purposes is prohibited and any reuse must be in consideration of the data provided in this material safety data sheet.
Suitable materials of construction: Glass lining, PVC, polypropylene, glass reinforced plastic, and polyethylene.
Unsuitable materials of construction: Mild steel, carbon steel, aluminum, and other metals.

8. Exposure Controls/Personal Protection

OSHA TWA ACGIH TWA: 15827-60-8 Diethylenetriaminepenta (methylenephosphonic acid) PEL: Not Established TLV:  Not established
OSHA TWA ACGIH TWA: 7647-01-0 Hydrochloric acid {Hydrogen chloride} CEIL: 5 ppm CEIL: 2 ppm)

Ventilation: Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
Eye protection: Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Clothing: Wear appropriate chemical resistant clothing.
Protective material types: Rubber
Respirator: Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any dust, mist and fume respirator. Any air-purifying respirator with a high-efficiency particulate filter. Any powered, air purifying respirator with a dust, mist and fume filter. Any powered, air-purifying respirator with a high-efficiency particulate filter.
For unknown concentrations or immediately dangerous to life or health – Any supplied-air respirator with full face-piece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full face-piece.

9. Physical and Chemical Properties

Appearance: Brown colored liquid
Odor: Characteristic
Solubility: Soluble in water and other polar solvents
Specific Gravity: 1.35 – 1.42
pH: <1
Boiling Point: >212 F
Melting Point: NA
Vapor Density (Air=1): No information found
Vapor Pressure (mm Hg): No information found
Evaporation Rate (BuAc=1): No information found

10. Stability and Reactivity

Stability: Is stable under ordinary conditions of use and storage. Stability decreases in the presence of moisture
Hazardous Decomposition Products: Phosphines, Carbon Monoxide, Carbon Dioxide, Nitrogen Oxides
Hazardous Polymerization: Will not occur
Incompatibilities: Reducing agents, strong oxidizing agents, metal salts of sulfites/sulfides, alkalis
Conditions to Avoid: Strong heat generation when combines with Alkalis

11. Toxicological Information

CAS 15827-60-8:
NTP: NA
IARC: NA
ACGIH: NA
OSHA : NA
CAS# 7647-01-0:
NTP: NA
IARC: 3
ACGIH: A4
OSHA : NA
Acute toxicity:
LC50, Inhalation, Mouse, 1108. PPM, 1 H.
TCLo, Inhalation, Rat, 685.0 UG/M3, 24 D.
Acute toxicity, LCLO, Inhalation, Human, 1300. PPM, 30 M.
Acute toxicity, LDLO, Route of Application: Unreported., Human, 81.00 MG/KG.
Eyes, Species: Rabbit, 5.000 MG, 30 S.

12. Ecological Information

CAS 15827-60-8
Environmental Fate: No information found.
Environmental Toxicity: No information found.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Domestic USA (Land, DOT USA) & ADR/RID:
Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Phosphonic acid, Hydrochloric acid)
Hazard Class: 8
UN/NA: UN3265
Packing Group: II
International (Water, I.M.O.)
Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Phosphonic acid, Hydrochloric acid)
Hazard Class: 8
UN/NA: UN3265
Packing Group: II

15. Regulatory Information

USA:
OSHA Status
: This material is classified as hazardous under OSHA regulations
HMIS (Perceived): Health Hazard: 3; Fire Hazard: 0; Reactivity: 1
NFPA(Perceived): Health:3; Flammability: 0; Reactivity: 1

Not listed on California Prop 65, CWA NPDES, Canadian NDSL, Mexico INSQ.

Listed on TSCA Inventory, Canadian DSL

16. Other Information

European Labeling in Accordance with EC Directives
H290 = May be corrosive to metals.
H314 = Causes severe skin burns and eye damage.
H318 = Causes serious eye damage.
H413 = May cause long lasting harmful effects to aquatic life.

C = Corrosive
Xi = Irritant
R34 = Causes burns.
R37/38 = Irritating to respiratory system and skin.
R38 = Irritating to skin.
R41 = Risk of serious damage to eyes.

Prepared by AJK on 15 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

DETA, DTPMP Phosphonate, diethylenetriamine penta methylene phosphonic acid Manufacturers:

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

Most products offered from our Houston & Midland Texas area warehouse

We solicit inquiries for warehousing, processing (blending, making solutions, sieving) & re-bagging needs on toll manufacturing basis.
We are looking for Technical Sales Representatives in New York, Chicago and Los Angeles Area.

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Palletized and Shrink Wrapped 25kg 50kg 55 lbs Export Import Palletized and Shrink Wrapped Drum PackingDTTMP DETA Phosphonate Scale Inhibitor

12 April, 2017