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Calcium Chloride Anhydrous SDS MSDS Sheet

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Calcium Chloride Anhydrous MSDS Sheet

Calcium Chloride Anhydrous
Technical & Pure.
Calcium Chloride Anhydrous

Calcium Chloride Anhydrous SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Calcium Dichloride; Calcium Di Chloride
CAS No.: 10043-52-4
EINECS: EC Number: 233-140-8.
Molecular Weight: 110.98
Chemical Formula: CaCl2 (Calcium Chloride Anhydrous)
Relevant Uses: Industrial use only.

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Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin irritation (Category 2)
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Symbol:Xi irritant
Risk Phrases: R36/37/38- Irritating to eyes, respiratory tract and skin..
For the full text of the S-statements R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Calcium Chloride Anhydrous
EINECS: EC Number: 233-140-8.
CAS No.: 10043-52-4
Percent: 93 - 100%

4. First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Oral ingestion may cause serum acidosis.

5. Fire Fighting Measures

Fire: Calcium Chloride is not considered to be a fire hazard.
Explosion: Calcium Chloride is not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.

7. Handling and Storage

Keep Calcium Chloride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Moist calcium chloride and concentrated solutions can corrode steel. When exposed to the atmosphere, calcium chloride will absorb water and form a solution.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards.

9. Physical and Chemical Properties

Appearance: Calcium Chloride is white or gray-white granules.
Odor: It is odorless.
Solubility: It is freely soluble in water, exothermic.
Density: Calcium Chloride has specific gravity of 2.15
pH: 8 - 9 Aqueous solution of Calcium Chloride
% Volatiles by volume @ 21C (70F): 0
Boiling Point: > 1600C (> 2912F)
Melting Point: 772C (1422F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Calcium Chloride is stable under ordinary conditions of use and storage. Substance will pick up moisture from the air and go into solution if exposed in open containers.
Hazardous Decomposition Products: It emits toxic chlorine fumes when heated to decomposition. Calcium Chloride may form hydrogen chloride in presence of sulfuric or phosphoric acids or with water at elevated temperatures.
Hazardous Polymerization: Will not occur.
Incompatibilities: Methyl vinyl ether, water, zinc, bromine trifluoride, mixtures of lime and boric acid, barium chloride, and 2-furan percarboxylic acid. Metals will slowly corrode in aqueous calcium chloride solutions. Aluminum (and alloys) and yellow brass will be attacked by calcium chloride.
Conditions to Avoid: Incompatibles.

11. Toxicological Information

Acute toxicity: Not classified
Skin corrosion/irritation: Not classified
Serious eye damage/irritation: Causes serious eye irritation.
Respiratory or skin sensitization: Not classified
Germ cell mutagenicity: Not classified
Carcinogenicity: Not classified
Reproductive toxicity: Not classified
Specific target organ toxicity (single exposure): Not classified
Specific target organ toxicity (repeated exposure): Not classified
Aspiration hazard: Not classified
Symptoms/injuries after inhalation: EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Slight irritation. Runny nose.
Symptoms/injuries after skin contact: Slight irritation.
Symptoms/injuries after eye contact: Irritation of the eye tissue. Visual disturbances.
Symptoms/injuries after ingestion: AFTER ABSORPTION OF HIGH QUANTITIES:

Toxicity to Animals: Oral rat LD50: 1000 mg/kg on Anhydrous CaCl2 basis.

12. Ecological Information

Toxicity to fish: LC50 - Lepomis macrochirus - 10650 mg/l - 96 h (on anhydrous basis)
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 2400 mg/l - 48 h
Environmental Fate: Based on available information for Calcium Chloride anhydrous, this material will not biodegrade or bio accumulate.
Environmental Toxicity: The LC50/96-hour values for fish are over 100 mg/l.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Calcium Chloride and unused contents in accordance with federal, state and local requirements.

14. Transport Information

DOT USA & ADR/RID: Not regulated.
IMDG: Not regulated.
IATA: Not regulated.
Canada TDG hazard class: Not regulated.
Europe ADR/RID hazard class: Not regulated.
ICAO/IATA (air) hazard class: Not regulated.

15. Regulatory Information

USA:
SARA 311/312:  Acute: Yes; Chronic: No; Fire: No; Pressure: No; Reactivity: No  (Pure / Solid)
TSCA: All components are listed or are exempt.
CERCLA Section 103 RQ (lb.): No
RCRA Section 261.33: No
Chemical Weapons Convention:  No; TSCA 12(b):  No; CDTA:  No
California Proposition 65: Not listed.

HMIS (Perceived):: Health Hazard: 2, Fire Hazard: 0, Reactivity: 1, Personal Protection: C
NFPA (Perceived):: Health: 2, Flammability: 0, Reactivity: 2
Protective Equipment:
Gloves (impervious). Synthetic apron. Wear appropriate respirator when ventilation is inadequate. Safety glasses.

Canada WHMIS (): CLASS D-2B: Material causing other toxic effects (TOXIC).

Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.

16. Other Information

European Labeling in Accordance with EC Directives:
EINECS EC Number: 233-140-8
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Xi irritant
R36/37/38- Irritating to eyes respiratory tract and skin..
Safety Phrases: R36/37/38- Irritating to eyes, respiratory system and skin. S22- Do not breathe dust. S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Prepared by AJK on 15 August 2016

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Calcium Chloride Anhydrous Manufacturers:

Finoric LLC
Houston, Midland & Pleasanton, Texas, USA.

Tel: 1-855-346-6742 (1-855-FINORIC)
Email:
info@finoric.com

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12 April, 2017