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Butylated Hydroxyanisole BHA SDS MSDS Sheet, Suppliers and Manufacturers' Representative

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BHA Butylated Hydroxyanisole Manufacturers Specifications and write-up

MSDS of BHA Butylated hydroxyanisole Manufacturers

Butylated Hydroxyanisole
Pure BHA
BHA Butylated Hydroxyanisole

BHA Butylated Hydroxyanisole SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Product Name/Synonyms: BHA or Butylated Hydroxyanisole or "tert-butyl-4-methoxyphenol (2-and 3-mixture)" or tert-butyl-p-methoxyphenol or "t-butyl hydroxyanisole", mono-tert-butyl-4-hydroxyanisole.
CAS No.: 25013-16-5
EINECS: EC Number: 246-563-8
Molecular Weight: 180.25
Chemical Formula: C11H16O2
Recommended uses and uses advised against (if any): Industrial Manufacturing.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA
In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2A)
Carcinogenicity (Category 2)
Specific target organ toxicity - single exposure (Category 3), Respiratory system

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Health Hazard
Health Hazard

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H315: Causes Skin Irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation
H351: Suspected of causing cancer.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi = Irritant
Xn = Harmful,
Risk Phrases:
R22 - Harmful if swallowed
R40 - Limited evidence of a carcinogenic effect
R36/37/38 - Irritating to eyes, respiratory system and skin

3. Composition/Information on Ingredients

Product Name/Synonyms: BHA or Butylated Hydroxyanisole or "tert-butyl-4-methoxyphenol (2-and 3-mixture)" or tert-butyl-p-methoxyphenol or "t-butyl hydroxyanisole", mono-tert-butyl-4-hydroxyanisole.
CAS No.: 25013-16-5
EINECS: EC Number: 246-563-8
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: May be combustible at high temperature..
Auto-Ignition Temperature: Not available.
Flash Points: 156C.
Flammable Limits: Not available.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Flammable in the presence of open flame.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Containers may explode on heating

6. Accidental Release Measures

Personal precautions, protective equipment, environmental precautions, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material. Keep away from drains, surface and groundwater and soil.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite), sweep up, and remove to an approved disposal container. Avoid touching the spilled material. Do not let the product enter drains. Do not contaminate the environment.

7. Handling and Storage

Precautions for safe handling: Do not ingest. Do not breathe dust. Apply according to good manufacturing and industrial hygiene practices with proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Use with adequate ventilation.  Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention. Minimize dust generation and accumulation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces. Containers of this material may be hazardous when empty since they retain product residues.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, reducing agents, metals, and acids. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not established.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Butylated Hydroxyanisole, BHA is a white to off-white waxy solid.
Odor: It has faint typical odor.
Odor threshold: Not available.
pH: Not available.
Relative density: about 1.05
Boiling Point: 264 - 270C.
Melting Point: 48 - 55C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is immiscible in water.
Viscosity: Not available.
Molecular Weight: 180.2
Molecular Formula: C11H16O2

10. Stability and Reactivity

Stability: Butylated Hydroxyanisole, BHA is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents metals and acids.
Conditions to Avoid
: Incompatibles and moisture.
Phenols are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides.
Avoid use of aluminum, copper and brass alloys in storage and process equipment.
Heat is generated by the acid-base reaction between phenols and bases.
Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature), these reactions generate heat.
Phenols are nitrated very rapidly, even by dilute nitric acid.
Nitrated phenols often explode when heated. Many of them form metal salts that tend toward detonation by rather mild shock.
Segregate from oleum, nitric acid and chlorosulfonic acid.

11. Toxicological Information

Acute toxicity: Toxic if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled.
Toxicity data
ORL-RAT LD50 > 2000 mg kg-1
ORL-MAM LD50 1100 mg kg-1
Carcinogenic Effects: Classified 2B (Possible for human.) by IARC. Classified 2 (Some evidence.) by NTP.
Mutagenic Effects: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: blood, liver, upper respiratory tract, skin.
Teratogenic Effects: Teratogenic effects have occurred in experimental animals.
Developmental Toxicity: Adverse reproductive effects have occurred in experimental animals.
May affect genetic material (mutagenic). May cause adverse reproductive effects based on animal test data. May cause cancer.

12. Ecological Information

Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
Products of Biodegradation: Possibly hazardous short-term degradation products are not likely. However, long term degradation products may arise.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

US DOT & ADR/RID Classification: Not Regulated
Canada TDG Classification: Not Regulated
IATA: Not Regulated

15. Regulatory Information

USA:
SARA 302 Components
: Not subject to the reporting under SARA Title III, Section 302.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard: No; Reactivity Hazard: No; Pressure Hazard: No; California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: BHA
California prop. 65 (no significant risk level): BHA: 4 mg/day (value)
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: BHA

Section 16 - Additional Information

European Labeling in Accordance with EC Directives
H302 = Harmful if swallowed.
H315 = Causes Skin Irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation
H351 = Suspected of causing cancer.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi = Irritant
Xn = Harmful,
Risk Phrases:
R22 - Harmful if swallowed
R40 - Limited evidence of a carcinogenic effect
R36/37/38 - Irritating to eyes, respiratory system and skin.

Prepared by AJK on 20 June 2020

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

 

Butylated Hydroxyanisole Manufacturers:

Finoric LLC
Beasley Houston Pleasanton Midland, Texas, USA.
Also Oklahoma, OK and Williston, ND USA

Tel: 1-855-346-6742 (1-855-FINORIC)
E-mail:
ask@finoric.com

We offer chemicals for industrial, laboratory and research use only. We are not drug dispensers or pharmacist. Our suppliers offer pharmaceutical grade products, manufactured under proper control for use in industries only.

Most products offered from our Houston TX, Midland TX, Pleasanton TX and Oklahoma, OK and Williston, ND area warehouse

We are looking for Technical Sales Representatives or Business Associates in New York, Williston North Dakota, Mansfield Pennsylvania, Zanesville, Ohio and Los Angeles Area, USA.

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BHA Butylated Hydroxyanisole Manufacturers

Butylated Hydroxyanisole Suppliers, Manufacturers, Exporters, Importers

27 September, 2021